Abstracts Chemistry

Temperature Dependence of Line Widths of the Inversion Spectra of Ammonia

by Charles E. Cook

One of the purposes of this work is to investigate modifications that have to be made to a standard source-modulation microwave spectrograph so that it can be used to study gases at various temperatures. Another objective in this work is to determine experimentally the function of temperature that describes how the line widths of microwave spectral lines vary with changing temperature. The most important segment of the study is the temperature dependence of the line width since from an accurate knowledge of this temperature dependence one is able to determine what molecular force fields are present and the relative importance of parts of the molecular force field.